- CAS
- Purity
- 103-56-0
- 99%
Location：Home > Agrochemicals
Top Quality Chinese Manufacturer supply 103-56-0 Cinnamyl propionate
- Molecular Formula: C12H14O2
- Molecular Weight: 190.242
- Vapor Pressure: 0.00136mmHg at 25°C
- Refractive Index: n20/D 1.535(lit.)
- Boiling Point: 297.4 °C at 760 mmHg
- Flash Point: 131.3 °C
- PSA： 26.30000
- Density: 1.037 g/cm3
- LogP: 2.65300
Cinnamyl propionate(Cas 103-56-0) Usage
|
Preparation |
By direct esterification of cinnamic alcohol with propionic acid under azeotropic conditions, or with propionic anhydride (Arctander, 1969). |
|
Flammability and Explosibility |
Notclassified |
|
Safety Profile |
Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. |
|
Taste threshold values |
Taste characteristics at 10 ppm: sweet, floral, waxy, balsamic, green, punch, grape and cherry. |
InChI:InChI=1/C12H14O2/c1-2-12(13)14-10-6-9-11-7-4-3-5-8-11/h3-9H,2,10H2,1H3/b9-6+
103-56-0 Relevant articles
Palladium-Catalyzed Three-Component Coupling Reaction of Allyl Carboxylates, Norbornenes and Diboronates Involving Sequential Olefins Insertion and Borylation Reaction
Li, Zun,Zheng, Jia,Li, Chunsheng,Wu, Wanqing,Jiang, Huanfeng
, p. 140 - 147 (2019)
An efficient Pd-catalyzed three-componen...
Cinnamyl alcohol fatty acid ester derivative and application and preparation method thereof
-
Paragraph 0040; 0041, (2019/05/08)
The invention relates to a derivative an...
Efficient Enzymatic Preparation of Flavor Esters in Water
Perdomo, Igor Chiarelli,Gianolio, Stefania,Pinto, Andrea,Romano, Diego,Contente, Martina Letizia,Paradisi, Francesca,Molinari, Francesco
, p. 6517 - 6522 (2019/06/20)
A straightforward biocatalytic method fo...
Synthesis of α-(Pentafluorosulfanyl)- and α-(Trifluoromethyl)-Substituted Carboxylic Acid Derivatives by Ireland-Claisen Rearrangement
Dreier, Anna-Lena,Beutel, Bernd,Mück-Lichtenfeld, Christian,Matsnev, Andrej V.,Thrasher, Joseph S.,Haufe, Günter
, p. 1638 - 1648 (2017/02/10)
Earlier studies have shown that [3,3]-si...
103-56-0 Process route
-
-
40630-85-1
cinnamyl 2-bromopropanoate
-
-
78761-38-3,103-56-0
cinnamyl propionate
-
-
256663-37-3
2-methyl-3-phenyl-pent-4-enoic acid
Conditions
| Conditions | Yield |
|---|---|
|
cinnamyl 2-bromopropanoate;
With
tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; indium(III) chloride; indium; chloro-trimethyl-silane; triethylamine;
at 10 - 30 ℃;
for 4h;
Inert atmosphere;
Sonication;
With
water; ammonium chloride;
In
tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone;
optical yield given as %de;
Saturated solution;
|
84%
16% |
|
cinnamyl 2-bromopropanoate;
With
tetrahydrofuran; indium(III) chloride; indium; chloro-trimethyl-silane; triethylamine;
at 10 - 30 ℃;
Inert atmosphere;
Sonication;
With
water; ammonium chloride;
In
tetrahydrofuran;
optical yield given as %de;
Saturated solution;
|
68%
32% |
-
-
104-54-1
3-Phenylpropenol
-
-
802294-64-0,79-09-4
propionic acid
-
-
78761-38-3,103-56-0
cinnamyl propionate
Conditions
| Conditions | Yield |
|---|---|
|
With
cerium(IV) trifluoromethanesulfonate;
at 25 ℃;
for 0.5h;
|
90%
|
|
With
dmap; dicyclohexyl-carbodiimide;
In
dichloromethane;
at 20 ℃;
Inert atmosphere;
|
89%
|
|
With
sodium tetrahydroborate;
Yield given. Multistep reaction;
2) 85 deg C to 90 deg C, 3 h;
|
|
|
With
dmap; S,S'-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate; triethylamine;
Yield given. Multistep reaction;
1.) ethyl acetate, 0 deg C, 30 min; 2.) room temp., 24 h;
|
103-56-0 Upstream products
-
104-54-1
3-Phenylpropenol
-
802294-64-0
propionic acid
-
40630-85-1
cinnamyl 2-bromopropanoate
-
105-37-3
Ethyl propionate
103-56-0 Downstream products
-
101-82-6
2-Benzylpyridine
-
80896-22-6
3-benzylamino-3-phenyl-1-propanol
-
232602-14-1
1-(2-benzyl-pyridin-3-yl)-ethanone
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1336877-38-3
2-benzylbenzo[h]quinoline